Super-dense packing of hydrogen molecules on a surface

Stuttgart – Hydrogen (H₂) is currently discussed as an ideal energy carrier in a world requiring renewable energies. Hydrogen has the highest gravimetric energy density of all chemical fuels (141 MJ/kg), which is three times higher than gasoline (46 MJ/kg). However, its low volumetric density restricts its widespread use in transportation applications —as current storage options require a lot of space.

At ambient temperature, hydrogen is a gas, and one kilogram of hydrogen occupies a volume of 12000 liters (12 cubic meters). In fuel-cell vehicles, hydrogen is stored under a very high pressure of 700 times the atmospheric pressure, which reduces the volume to 25 liters per kilogram of H₂. Liquid hydrogen shows a higher density resulting in 14 liters per kilogram, but it requires extremely low temperatures since the boiling point of hydrogen is minus 253 ^°C.

Now a team of scientists from the Max Planck Institute for Intelligent Systems, the Technische Universität Dresden, the Friedrich-Alexander-Universität Erlangen-Nürnberg, and Oak Ridge National Laboratory has demonstrated that hydrogen condenses on a surface at a very low temperature near the H₂ boiling point, forming a super-dense monolayer exceeding the density of liquid hydrogen by a factor of almost three, which reduces the volume to only 5 liters per kilogram H₂.

The surprising result was that twice as many H₂ molecules than atoms of the noble gas argon covered the surface, even though both have nearly the same size. To double the number of molecules per area, H₂ molecules squeeze closely together, forming a super-dense layer.

The study by R. Balderas-Xicohténcatl  et al. involved high-resolution cryo-adsorption experiments on highly-ordered mesoporous silica exhibiting well-defined pore and surface characteristics to determine the number of molecules condensed on the material’s surface.

Inelastic neutron scattering is an ideal tool to follow the formation of this two-dimensional hydrogen layer. For the first time, the existence of this super-dense hydrogen was confirmed in situ. This direct observation was only possible using the high-resolution neutron vibrational spectrometer VISION, which features an inelastic count rate more than 100 times greater than any similar available spectrometer.

Theoretical studies confirm the experimental observations of the unusually high hydrogen density in the adsorbed layer. The attractive forces at the surface were stronger than the repulsion between two hydrogen molecules resulting in a super-dense hydrogen packing on the mesoporous silica surface. The super-high density is a consequence of the high compressibility of hydrogen, which doesn’t have core electrons.

The formation of the super-dense hydrogen layer at low temperatures near the boiling point is of fundamental interest. It should be considered for quantitative analysis of H₂ adsorption isotherms at 20 K. It may also open new possibilities for enhancing the volumetric capacity of cryogenic hydrogen storage systems for many applications in a coming hydrogen economy.

Original publication:

Rafael Balderas-Xicohténcatl, Hung-Hsuan Lin, Christian Lurz, Luke Daemen, Yongqiang Cheng, Katie Cychosz Struckhoff, Remy Guillet-Nicolas, Gisela Schütz, Thomas Heine, Anibal J. Ramirez-Cuesta, Matthias Thommes, Michael Hirscher. Formation of a super-dense hydrogen monolayer on mesoporous silica. Nature Chemistry. https://doi.org/10.1038/s41557-022-01019-7